Activation of a CH bond in polypyridine systems by acetyl hypofluorite made from F2.
نویسندگان
چکیده
Activation of the relatively inactive polypyridine backbone with strong electrophilic fluorine, originating from acetyl hypofluorite (AcOF) enables attack of the acetoxy moiety at the α position to the heteroatom. Derivatives of bipyridine, phenanthroline and terpyridine systems have been acetoxylated or oxygenated within a few minutes usually in very good yields.
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ورودعنوان ژورنال:
- Organic & biomolecular chemistry
دوره 10 9 شماره
صفحات -
تاریخ انتشار 2012